The New Physics and Its Evolution by Lucien Poincare
page 79 of 282 (28%)
page 79 of 282 (28%)
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definition is admitted, we arrive, by taking as a basis the principles
set forth at the inception, at the demonstration of the celebrated theorem of Clausius: _The entropy of a thermally isolated system continues to increase incessantly._ It is very evident that the theorem can only be worth applying in cases where the entropy can be exactly defined; but, even when thus limited, the field still remains vast, and the harvest which we can there reap is very abundant. Entropy appears, then, as a magnitude measuring in a certain way the evolution of a system, or, at least, as giving the direction of this evolution. This very important consequence certainly did not escape Clausius, since the very name of entropy, which he chose to designate this magnitude, itself signifies evolution. We have succeeded in defining this entropy by demonstrating, as has been said, a certain number of propositions which spring from the postulate of Clausius; it is, therefore, natural to suppose that this postulate itself contains _in potentia_ the very idea of a necessary evolution of physical systems. But as it was first enunciated, it contains it in a deeply hidden way. No doubt we should make the principle of Carnot appear in an interesting light by endeavouring to disengage this fundamental idea, and by placing it, as it were, in large letters. Just as, in elementary geometry, we can replace the postulate of Euclid by other equivalent propositions, so the postulate of thermodynamics is not necessarily fixed, and it is instructive to try to give it the most general and suggestive character. |
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