Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 102 of 352 (28%)
page 102 of 352 (28%)
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when the product is to be used at high temperatures. By means of rollers
steam heated, the incorporation may be accomplished without the aid of a volatile liquid, or the nitro-cellulose may be employed wet, the water being removed after "solution." It is advisable to use the cellulose nitrated only just enough to render it suitable, in order to reduce the inflammability of the finished product. Mr W. Allen, M.P., of Gateshead, proposed to use celluloid for cartridge cases, and thus to lighten ammunition, and prevent jambing, for the case will be resolved into gases along with the powder. Extractors will also be done away with. ~Celluloid~ is an intimate mechanical mixture of pyroxyline (gun-cotton or collodion-cotton) with camphor, first made by Hyatt, of Newark, U.S.A., and obtained by adding the pyroxyline to melted camphor, or by strongly compressing the two substances together, or by dissolving the constituents in an appropriate solvent, e.g., alcohol or ether, and evaporating to dryness. A combination of the two latter methods, i.e., partial solution, with pressure, is now usually adapted. The pyroxyline employed is generally the tetra- and penta-nitrated cellulose, the hexa-nitrate (gun-cotton) being but seldom used on account of its explosive properties. Care is taken to prevent the formation of the hexa-nitrate by immersing the cellulose in only moderately strong nitric acid, or in a warm mixture of nitric and sulphuric acids. The paper, either in small pieces or in sheets, is immersed for about twenty-five minutes in a mixture of 2 parts of nitric acid and 5 parts of sulphuric acid, at a temperature of about 30° C., after which the nitrated cellulose is thoroughly washed with water to remove the last traces of free acid, pressed, and whilst still moist, mixed with the camphor. |
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