Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 113 of 352 (32%)
page 113 of 352 (32%)
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addition of alcohol, a solution is at once obtained, and the granular
appearance disappears, and the solution becomes homogeneous. The acid mixture and the method of nitrating have much to do with the action of the various solvents, so also has the presence of water. Dr Schupphaus found that propyl and isobutyl alcohols with camphor were active solvents, and the ketones, palmitone, and stearone in alcohol solution, also alpha- and beta-naphthol, with alcohol and anthraquinone (diphenylene diketone) in alcoholic solution, and also iso-valeric aldehyde and its derivatives, amyliden-dimethyl and amyliden-diethyl ethers. August Sayer (U.S.P., No. 470,451) finds diethyl-ketone, dibutyl-ketone, di-pentyl-ketone, and the mixed ketones,[A] methyl-ethyl, methyl-propyl, methyl-butyl, methyl-amyl, and ethyl-butyl ketones are active solvents of pyroxyline; and Paget finds that although methyl-amyl oxide is a solvent, that ethyl-amyl oxide is not. [Footnote A: Ketones are derived from the fatty acids by the substitution of the hydroxyl of the latter by a monad positive radical. They thus resemble aldehydes in constitution. The best-known ketone is acetone CH_{3}CO.CH_{3}. Mixed ketones are obtained by distilling together salts of two different fatty acids. Thus potassic butyrate and potassic acetate form propyl-methyl-ketone-- C(C_{2}H_{5})H_{2} | CO.CH_{3}] The solvents of pyroxyline can be divided into general classes--First, |
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