Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 114 of 352 (32%)
page 114 of 352 (32%)
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those which are solvents without the aid of heat or solution in alcohol;
second, those that are solvents when dissolved in alcohol. These solvents are those which also develop a solvent action when heated to their melting point in combination with pyroxyline. Mr W.D. Field groups the solvents of pyroxyline into classes thus: Two of the monohydric alcohols; compound ethers of the fatty acids with monohydric alcohols, aldehydes; simple and mixed ketones of the fatty acid series. These four classes include the greater number of the solvents of pyroxyline. Those not included are as follows:--Amyl-nitrate and nitrite, methylene-di-methyl ether, ethidene-diethyl ether, amyl-chloracetate, nitro-benzene and di-nitro-benzene, coumarin, camphor, glacial acetic acid, and mono-, di-, and tri-acetin. Richard Hale uses the following solvent:--Amyl-acetate, 4 volumes; petroleum naphtha, 4 volumes; methyl-alcohol, 2 volumes; pyroxyline, 4 to 5 ounces to the gallon of solvent. Hale used petroleum naphtha to hasten the drying qualities of the varnish, so that it would set on the article to be varnished before it had a chance to run off. It is, however, the non-hygroscopic character of the solvent that makes the varnish successful. This formula is very largely used for the production of pyroxyline varnish, which is used for varnishing pens, pencils, &c., also brass-work and silver-ware. The body known as oxy-cellulose[A] is formed by the action of nitric acid upon cellulose when boiled with it. The quantity formed is about 30 per cent. of cellulose acted upon. When washed free from acid, it gelatinises. It is then soluble in dilute alkalies, and can be reprecipitated from solution by alcohol, acids, or saline solutions. Messrs Cross and Bevan assign to it the formula C_{18}H_{26}O_{16}. It dissolves in concentrated |
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