Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 115 of 352 (32%)
page 115 of 352 (32%)
![]() | ![]() |
|
|
sulphuric acid, and with nitric acid forms a nitro body of the formula
C_{18}H_{23}O_{16}3(NO_{2}), which is prepared as follows:--The gelatinous oxy-cellulose is washed with strong nitric acid until free from water, and is then diffused through a mixture of equal volumes of strong sulphuric and nitric acids, in which it quickly dissolves. The solution, after standing for about an hour, is poured in a fine stream into a large volume of water, by which the "nitro" body is precipitated as a white flocculent mass. The product, after drying at 110° C., was found upon analysis to contain 6.48 per cent. nitrogen. [Footnote A: "On the Oxidation of Cellulose," by C.F. Cross and E.J. Bevan, _Jour. Chem. Soc._, 1883, p. 22.] MISCELLANEOUS NITRO-EXPLOSIVES. ~Nitro-Starch.~--It is only recently that, by means of the process introduced by the "Actiengesellschaft Dynamit Nobel," it has been possible to make this explosive upon the manufacturing scale. Nitro-starch has been known since 1883, when Braconnot discovered it, and called it xyloidine. Its formula is C_{6}H_{8}O_{3}(NO_{3})_{2}, but Dr Otto Mühlhäusen has lately succeeded in preparing higher nitrated compounds, viz.:-- (_a._) C_{6}H_{7-1/2}O_{2-1/2}(NO_{3})_{2-1/2}. (_b._) C_{6}H_{7}O_{4}(NO_{3})_{3}. Or doubling the molecule of starch:-- Nitrogen. i. Tetra-nitro-starch C_{12}H_{16}O_{6}(ONO_{2})_{4} 11.11 per cent. |
|


