Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 149 of 352 (42%)
page 149 of 352 (42%)
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odour of bitter almonds. It solidifies in the cold. In di-nitro-benzene,
the two nitro groups may be in the meta, ortho, or para position, the meta position being the most general (see fig., page 4). By recrystallising from alcohol, pure meta-di-nitro-benzene may be obtained in long colourless needles. The ortho compound crystallises in tables, and the para in needles. They are both colourless. When toluene is nitrated, the para and ortho are chiefly formed, and a very little of the meta compound. ~Nitro Compounds of Benzene and Toluene.~--The preparation of the nitro derivatives of the hydrocarbons of the benzene series is very simple. It is only necessary to bring the hydrocarbon into contact with strong nitric acid, when the reaction takes place, and one or more of the hydrogen atoms of the hydrocarbon are replaced by the nitryl group (NO_{2}). Thus by the action of nitric acid on benzene (or benzol), mono-nitro-benzene is formed:-- C_{6}H_{6} + HNO_{3} = C_{6}H_{5}.NO_{2} +H_{2}O. Mono-nitro-benzene. By the action of another molecule of nitric acid, the di-nitro-benzene is formed:-- C_{6}H_{5}.NO_{2} + HNO_{3} = C_{6}H_{4}(NO_{2})_{2} + H_{2}O. Di-nitro-benzene. These nitro bodies are not acids, nor are they ethereal salts of nitrous acid, as nitro-glycerine is of glycerine. They are regarded as formed from nitric acid by the replacement of hydroxyl by benzene radicals. ~Mono-nitro Benzene~ is made by treating benzene with concentrated nitric |
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