Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 289 of 352 (82%)
page 289 of 352 (82%)
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placed in a beaker of water on a tripod, will maintain the temperature of
the water during four or five hours within 0.2° C., and an air bath during six weeks within 0.5° C. To sum up briefly the method of using the regulator:--Being filled with mercury to about 1\2 inch below the T, attach the gas supply as in diagram (Fig. 2), the brass tap being open, and the tube B unclosed by the mercury. Allow the gas to completely expel the air in the apparatus. Push down the tube A so that the end of B is well under the surface of the mercury. Turn off the tap of the bye-pass until the smallest bead of flame is visible. Raise A and B, and allow the temperature to rise until the desired point is attained. Then push the tubes A and B slowly down until the flame is just shut off. The regulator will then keep the temperature at that point. ~Will's Test for Nitro-Cellulose.~--The principle of Dr W. Will's test[A] may be briefly described as follows:--The regularity with which nitro- cellulose decomposes under conditions admitting of the removal of the products of decomposition immediately following their formation is a measure of its stability. As decomposing agent a sufficiently high temperature (135° C.) is employed, the explosive being kept in a constantly changing atmosphere of carbon dioxide, heated to the same temperature: the oxides of nitrogen which result are swept over red-hot copper, and are then reduced to nitrogen, and finally, the rates of evolution of nitrogen are measured and compared. Dr Will considers that the best definition and test of a stable nitro-cellulose is that it should give off at a high temperature equal quantities of nitrogen in equal times. For the purposes of manufacture, it is specially important that the material should be purified to its limit, i.e., the point at which further washing produces no further change in its speed of decomposition measured |
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