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Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 73 of 352 (20%)
flat wood fixed on a broom-handle. It is then packed away in galvanised-
iron air-tight cases, and is ready for the next operation. At some works
the cotton is dried upon shelves in a drying house through which hot air
circulates, the shelves being of canvas or of brass wire netting. The hot
air must pass under the shelves and through the cotton, or the process
will be a very slow one.

~Dipping and Steeping.~--The dry cotton has now to be nitrated. This is
done by dipping it into a mixture of nitric and sulphuric acids. The acids
used must be strong, that is, the nitric acid must be at least of a
gravity of 1.53 to 1.52, and should contain as little nitric oxide as
possible. The sulphuric acid must have a specific gravity of 1.84 at 15°
C., and contain about 97 per cent. of the mono-hydrate (H_{2}SO_{4}). In
fact, the strongest acids obtainable should be used when the product
required is gun-cotton, i.e., the highest nitrate.

The sulphuric acid takes no part in the chemical reaction involved, but is
necessary in order to combine with the water that is liberated in the
reaction, and thus to maintain the strength of the nitric acid. The
reaction which takes place is the following:--

2(C_{6}H_{10}O_{5}) + 6HNO_{3} = C_{12}H_{14}(NO_{3})_{6} + 6 H_{2}O.
324 378 = 594 108.
Cellulose. Gun-Cotton.

Theoretically,[A] therefore, 1 part of cellulose should form 1.8 part of
gun-cotton. Practically, however, this is never obtained, and 1.6 lb. from
1 lb. of cellulose is very good working. The mixture of acids used is
generally 1 to 3, or 25 per cent. nitric acid to 75 per cent. sulphuric
acid.
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