Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 91 of 352 (25%)
page 91 of 352 (25%)
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will have a low nitrogen content, whereas a material with as high a
nitrogen as 12 or 12.6 is to be aimed at. [Footnote A: Raw cotton is often used.] The cotton should not be allowed to remain in the dipping tanks for more than five minutes, and the acid mixture should be kept at a temperature of 28° C. or thereabouts; and the cotton should be removed after a few minutes, and should not be pressed out, as in the case of gun-cotton, but at once transferred to the pots and allowed to steep for forty-eight hours. (Some prefer twenty-four hours, but there is more chance in this case of the product containing non-nitrated cellulose.) When the nitration is complete, the collodion-cotton is removed from the pots, and treated in exactly the same manner as described under gun-cotton. The produce should be entirely soluble in ether-alcohol and nitro-glycerine, and contain as near 12.7 per cent. of nitrogen as possible. The theoretical nitrogen is for the penta-nitro-cellulose 12.75 per cent. This will, however, seldom if ever be obtained. The following are some of the results I have obtained from different samples:-- Nitrogen. (1.) (2.) (3.) German make 11.64 11.48 11.49 per cent. Stowmarket 12.57 12.60 11.22 " Walsrode 11.61 12.07 11.99 " Faversham 12.14 11.70 11.60 " and the following was the analysis of a sample (No. 1) of German-made collodion-cotton, which made very good blasting gelatine:-- |
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