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The Elements of Geology by William Harmon Norton
page 57 of 414 (13%)
cones and mounds of the geysers in the Yellowstone National Park
and in Iceland have been formed.

Where water oozes from the earth one may sometimes see a rusty
deposit on the ground, and perhaps an iridescent scum upon the
water. The scum is often mistaken for oil, but at a touch it
cracks and breaks, as oil would not do. It is a film of hydrated
iron oxide, or LIMONITE, and the spring is an iron, or chalybeate,
spring. Compounds of iron have been taken into solution by ground
water from soil and rocks, and are now changed to the insoluble
oxide on exposure to the oxygen of the air.

In wet ground iron compounds leached by ground water from the soil
often collect in reddish deposits a few feet below the surface,
where their downward progress is arrested by some impervious clay.
At the bottom of bogs and shallow lakes iron ores sometimes
accumulate to a depth of several feet.

Decaying organic matter plays a large part in these changes. In
its presence the insoluble iron oxides which give color to most
red and yellow rocks are decomposed, leaving the rocks of a gray
or bluish color, and the soluble iron compounds which result are
readily leached out,--effects seen where red or yellow clays have
been bleached about some decaying tree root.

The iron thus dissolved is laid down as limonite when oxidized, as
about a chalybeate spring; but out of contact with the air and in
the presence of carbon dioxide supplied by decaying vegetation, as
in a peat bog, it may be deposited as iron carbonate, or SIDERITE.

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