The Story of the Soil; from the Basis of Absolute Science and Real Life, by Cyril G. (Cyril George) Hopkins
page 132 of 371 (35%)
page 132 of 371 (35%)
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L., is meant tricalcium phosphate, a compound which contains exactly
twenty per cent. of phosphorus. Thus, you can always divide the guaranteed percentage of 'bone phosphate of lime' by five, and the result will be the per cent. of phosphorus. "As stated in your Century dictionary, true phosphoric acid forms three distinct classes of salts, because either one, two, or all of the three hydrogen atoms may be replaced by a metallic element. Thus, we have phosphoric acid itself containing the three hydrogen atoms, one phosphorus atom, and four oxygen atoms. This might be called trihydrogen phosphate (H3PO4). Now if one of the hydrogen atoms is replaced by one potassium atom, we have potassium dihydrogen phosphate (KH2PO4); with two potassium atoms and one hydrogen, we have dipotassium hydrogen phosphate (K2HPO4); and if all hydrogen is replaced by potassium the compound is tripotassium phosphate (K3PO4). To make similar salts with two-handed metallic elements, like calcium or magnesium, we need to start with two molecules of phosphoric acid H6(PO4)2; because each atom of calcium will replace two hydrogen atoms. Thus we have mono calcium phosphate, CaH4(PO4)2, dicalcium phosphate, Ca2H2(PO4)2, and tricalcium phosphate, Ca3(PO4)2. It goes without saying that monocalcium phosphate contains four atoms of hydrogen and that dicalcium phosphate contains two hydrogen atoms. By knowing the atomic weights (40 for calcium, 31 for phosphorus, and 16 for oxygen), it is easy to compute that the molecule of tricalcium phosphate weighs 310 of which 62 is phosphorus. This is exactly one-fifth, or twenty per cent. This compound you will remember is sometimes called 'bone phosphate of lime'. It is also called simply 'bone phosphate'; because it is the phosphorus compound contained in bones. It is sometimes called lime phosphate, although it contains |
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