Scientific American Supplement, No. 363, December 16, 1882 by Various
page 40 of 145 (27%)
page 40 of 145 (27%)
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are boiled, the carbonic acid is driven off, and the salts, deprived of
their solvent, are rapidly precipitated in fine crystalline particles, which adhere tenaciously to whatever surface they fall upon. With respect to the sulphate of lime, the case is different. It is at best only sparingly soluble in water, one part (by weight) of the salt requiring nearly 500 parts of water to dissolve it. As the water evaporates in the boiler, however, a point is soon reached where supersaturation occurs, as the water freshly fed into it constantly brings fresh accessions of the salt; and when this point is reached, the sulphate of lime is precipitated in the same form and with the same tenaciously adherent quality as the carbonates. There is, however, a peculiar property possessed by this salt which facilitates its precipitation, namely, that its solubility in water diminishes as the temperature rises. This fact is of special interest, since, if properly taken advantage of, it is possible to effect its almost complete removal from the feed-water of boilers, There is little difference in the solubility of the sulphate of lime until the temperature has risen somewhat above 212 deg. Fahr., when it rapidly diminishes, and finally, at nearly 300 deg., all of this salt, held in solution at lower temperatures, will be precipitated when the temperature has risen to that point. The following table[1] represents the solubility of sulphate of lime in sea water at different temperatures: Temperature. Percentage Sulph. Fahr. Lime held in Solution. 217 deg. 0.500 219 deg. 0.477 221 deg. 0.432 |
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