Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 64 of 352 (18%)
page 64 of 352 (18%)
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nitrogen.
Penta-nitro-cellulose C_{24}H_{35}O_{20}(NO_{2})_{5} = 8.04 per cent. nitrogen. Tetra-nitro-cellulose C_{24}H_{36}O_{20}(NO_{2})_{4} = 6.77 per cent. nitrogen. (= old mono-nitro-cellulose) It is not unlikely that a long series of nitrates exists. It is at any rate certain that whatever strength of acids may be used, and whatever temperature or other conditions may be present during the nitration, that the product formed always consists of a mixture of the soluble and insoluble nitro-cellulose. Theoretically 100 parts of cotton by weight should produce 218.4 parts of gun-cotton, but in practice the yield is a good deal less, both in the case of gun-cotton or collodion-cotton. In speaking of soluble and insoluble nitro-cellulose, it is their behaviour, when treated with a solution consisting of 2 parts ether and 1 of alcohol, that is referred to. There is, however, another very important difference, and that is their different solubility in nitro-glycerine. The lower nitrates or soluble form is soluble in nitro-glycerine under the influence of heat, a temperature of about 50° C. being required. At lower temperatures the dissolution is very imperfect indeed; and after the materials have been left in contact for days, the threads of the cotton can still be distinguished. The insoluble form or gun-cotton is entirely _insoluble_ in nitro-glycerine. It can, however, be made to dissolve[A] by the aid of acetone or acetic ether. Both or rather all the forms of nitro-cellulose can be dissolved in acetone or acetic ether. They also dissolve in concentrated sulphuric acid, and the penta-nitrate in nitric acid at about 80° or 90° C. |
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