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Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 65 of 352 (18%)
[Footnote A: Or rather to form a transparent jelly.]

The penta-nitrate may be obtained in a pure state by the following
process, devised by Eder:--The gun-cotton is dissolved in concentrated
nitric acid at 90° C., and reprecipitated by the addition of concentrated
sulphuric acid. After cooling to 0° C., and mixing with a larger volume of
water, the precipitated nitrate is washed with water, then with alcohol,
dissolved in ether-alcohol, and again precipitated with water, when it is
obtained pure. This nitrate is soluble in ether-alcohol, and slightly in
acetic acid, easily in acetone, acetic ether, and methyl-alcohol,
insoluble in alcohol. Strong potash (KOH) solution converts into the
di-nitrate C_{12}H_{18}O_{8}(NO_{3})_{2}. The hexa-nitrate is not soluble
in acetic acid or methyl-alcohol.

The lower nitrates known as the tetra- and tri-nitrates are formed
together when cellulose is treated with a mixture of weak acids, and
allowed to remain in contact with them for a very short time (twenty
minutes). They cannot be separated from one another, as they all dissolve
equally in ether-alcohol, acetic ether, acetic acid, methyl-alcohol,
acetone, amyl acetate, &c.

As far as the manufacture of explosive bodies is concerned, the two forms
of nitro-cellulose used and manufactured are gun-cotton or the hexa-
nitrate (once regarded as tri-nitro-cellulose), which is also known as
insoluble gun-cotton, and the soluble form of gun-cotton, which is also
known as collodion, and consists of a mixture of several of the lower
nitrates. It is probable that it chiefly consists, however, of the next
highest nitrate to gun-cotton, as the theoretical percentage of nitrogen
for this body,. the penta-nitrate, is 12.75 per cent., and analyses of
commercial collodion-cotton, entirely soluble in ether-alcohol, often give
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